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Paul Houston Current Research
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Hydrogen Atom Transfer ReactionsH atom abstraction by fluorine atoms is a reaction important in chemical lasers and for comparison to high-level theory. We studied this process as a function of temperature for several important reactions during the 1970s. Our paper concerning the activation energy for the F + H2 reaction is still quoted, and the non-Arrhenius tempertature dependence of other F + HX reactions may have importance to the current understanding of non-adiabatic effects.The figure above shows the temperature dependence of the F + HCl rate constant.
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